Reactions of 1-Heptafluoropropylmagnesium Bromide. II. 1 The Synthesis of Fluorine-containing Olefins and of 1-Heptafluoropropylbenzene

ET McBee, CW Roberts, AF Meiners

Index: McBee et al. Journal of the American Chemical Society, 1953 , vol. 75, p. 2324 Journal of the American Chemical Society, 1957 , vol. 79, p. 335

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Citation Number: 41

Abstract

Discussion Few (perfluoroalky1)-benzenes other than trifluoromethylbenzene have been synthesized. In an attempt to synthesize l-heptafluoropropylbenzene, heptafluoro-1- iodopropane was treated with pheriylmagnesium bromide, phenyllithi~ m,~ phenylsodium and phenylcalcium iodide. However, no evidence of coupling was observed, the predominant reaction in each case being an exchange. 1-Heptafluoropropylbenzene was ...