Polyhedron

Inner sphere complexes derived from the coordinate interactions of tin (iv) isothiocyanate moieties with 1-[(4-methylphenylimino) methyl]-2-phenol. crystal structure of …

GY Yeap, SG Teoh, SB Teo, SC Loh, HK Fun

Index: Yeap, Guan-Yeow; Teoh, Siang-Guan; Teo, Soon-Beng; Loh, Saow-Chen; Fun, Hoong-Kun Polyhedron, 1996 , vol. 15, # 22 p. 3941 - 3946

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Citation Number: 23

Abstract

A series of neutral complexes derived from the reactions of Sn (NCS) 4, PhSn (NCS) 3 and R2Sn (NCS) 2 (R= Me and Ph) with [1-[(4-methylphenylimino) methyl]-2-phenol] have been synthesized. An X-ray crystal structural study of the diisothiocyanatodimethyltin (IV) derivative has been performed and all synthesized compounds were characterized by IR, 1H and 13C NMR spectroscopies. All the complexes exhibit octahedral geometry with tin- ...