Hydrogenolysis of unsaturated phosphate esters
A Jung, R Engel
Index: Jung,A.; Engel,R. Journal of Organic Chemistry, 1975 , vol. 40, # 25 p. 3652 - 3654
Full Text: HTML
Citation Number: 10
Abstract
A series of unsaturated phosphate esters has been synthesized and subjected to hydrogenolysis over Adams catalyst. It has been demonstrated that direct hydrogenolysis of vinylic esters occurs yielding the phosphoric acid and the alkene; the alkene is then further reduced to the alkane. It has also been shown that migration of a" distant" olefinic linkage to a site subject to hydrogenolysis occurs at a rate such that cleavage product may be ...
Related Articles:
The preparation of alkylaryldichlorocyclopropanol phosphates
[Xi, Qi; Lin, Xingji; Chang, Jianhua; Ding, Yixiang Phosphorus, Sulfur and Silicon and the Related Elements, 2003 , vol. 178, # 1 p. 47 - 54]
Reaction of triflates with potassium diethyl phosphite. Formation of phosphate esters
[Creary, Xavier; Benage, Brigitte; Hilton, Kathryn Journal of Organic Chemistry, 1983 , vol. 48, # 17 p. 2887 - 2891]