New methods for the synthesis of fluoroolefins via the palladium catalyzed cross-coupling reaction of 1-fluorovinyl halides with organoboranes and organostannanes

…, K Wilcoxen, CQ Huang, N Strack, JR McCarthy

Index: Chen, Chen; Wilcoxen, Keith; Huang, Charles Q.; Strack, Nathalie; McCarthy, James R. Journal of Fluorine Chemistry, 2000 , vol. 101, # 2 p. 285 - 290

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Citation Number: 50

Abstract

The palladium catalyzed cross-coupling reaction of 1-fluorovinyl halides with organoboranes and organostannanes provide two new facile methods to 1-substituted 1- fluoroolefins. The reactions proceed with retention of configuration in good to excellent yields.

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