Free-radical chemistry of organophosphorus compounds. III.. alpha. vs.. beta. Scission in reactions of alkoxy and thiyl radicals with trivalent organophosphorus …
WG Bentrude, ER Hansen, WA Khan…
Index: Bentrude,W.G. et al. Journal of the American Chemical Society, 1973 , vol. 95, p. 2286 - 2293
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Citation Number: 22
Abstract
Abstract: Reactions of a series of XP (OEt) 2 (where X= C1, alkyl, Ph, PhO, AcO, and n- Bu2N) with alkoxy and thiyl radicals (RA., A= 0 or S) have been studied to attempt to understand more fully the factors which determine the relative amounts of oxidation [APX (OEt) 2] and displacement [RAP (OEt) 2] products which result in such systems. With A= 0, both oxidation and displacement take place depending on the natures of R and X. ...
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