Nitrolysis of 1, 3, 5-tris (β-cyanoethyl) hexahydro-s-triazine

V Kadeřábek, J Denkstein

Index: Kaderabek,V.; Denkstein,J. Collection of Czechoslovak Chemical Communications, 1977 , vol. 42, p. 711 - 717

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Citation Number: 2

Abstract

Nitrolysis of 1, 3, 5-trisW-cyanoethyl) hexahydro-s-triazine (I) has been studied in nitric acid- acetic anhydride medium, when a mixture of N-acetoxymethyl-3-nitraminopropionitrile (Ill) and 4, 6-dinitro-4, 6-diazanonanedioic acid dinitrile (IX) is formed predominantly. Ratio of the both main reaction products 111 and 1 X is markedly affected especially by acidity of the reaction medium. Yields of the dinitrile IX can positively be influenced by the presence of ...