Reducing versus basic properties of 1, 2-diaryl-1, 2-disodioethanes
U Azzena, G Dettori, L Pisano, M Pittalis
Index: Azzena, Ugo; Dettori, Giovanna; Pisano, Luisa; Pittalis, Mario Tetrahedron, 2011 , vol. 67, # 19 p. 3470 - 3475
Full Text: HTML
Citation Number: 5
Abstract
Abstract The outcome of the reaction between halogenated arylacetic acids and 1, 2-diaryl- 1, 2-disodioethanes strongly depends on the nature of both reaction partners, and it can be rationalized in terms of a competition between reducing and basic properties of the vic- diorganometals, as well as of the ease of the reductive cleavage of the different carbon– halide bonds. As an application of these findings, we developed a particularly mild ...
Related Articles:
[Ito, Rina; Umezawa, Naoki; Higuchi, Tsunehiko Journal of the American Chemical Society, 2005 , vol. 127, # 3 p. 834 - 835]
Iodide-catalyzed reductions: development of a synthesis of phenylacetic acids
[Milne, Jacqueline E.; Storz, Thomas; Colyer, John T.; Thiel, Oliver R.; Dilmeghani Seran, Mina; Larsen, Robert D.; Murry, Jerry A. Journal of Organic Chemistry, 2011 , vol. 76, # 22 p. 9519 - 9524]
A new biocatalyst for the preparation of enantiomerically pure 2-arylpropanoic acids
[Kumar, Ish; Manju, Kavita; Jolly, Ravinder S. Tetrahedron Asymmetry, 2001 , vol. 12, # 10 p. 1431 - 1434]
Highly regioselective iron-promoted hydrocarboxylation of styrene
[Brunet, Jean-Jacques; Neibecker, Denis; Srivastava, Radhey S. Tetrahedron Letters, 1993 , vol. 34, # 17 p. 2759 - 2762]
Cobalt-catalyzed low pressure double carbonylation of aryl and secondary benzyl halides
[Francalanci, F.; Bencini, E.; Gardano, A.; Vincenti, M.; Foa, M. Journal of Organometallic Chemistry, 1986 , vol. 301, p. C27 - C30]