Highly Branched Molecules. III. The Preparation of Tri-t-butylcarbinol by Means of t-Butyllithium

PD Bartlett, EB Lefferts

Index: Bartlett; Swain Journal of the American Chemical Society, 1955 , vol. 77, p. 2801

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Citation Number: 36

Abstract

When t-butyllithium was first prepared'it was found to yield only reduction product on reaction with hexamethylacetone. The preparation of tri-tbutylcarbinol using t-butyl chloride and sodium2 has been successfully repeated3 but the yields were always poor. We have found that the handling of t-butyllithium at temperatures below-40'not only makes possible the preparation of this organometallic compound in ether with reliably high yields4 but ...