Synthetic Communications

Preparation of α-Halovinyl Sulfides by Eliminative Deoxygenation of α-Halosulfoxides

RD Miller, R Hässig

Index: Moller, R. D.; Haessig, R. Synthetic Communications, 1984 , vol. 14, # 14 p. 1285 - 1290

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Citation Number: 9

Abstract

Abstract Vinyl sulfides are useful synthetic intermediates1 which have received increasing attention recently both as masked carbonyl moieties2 and in carbon-carbon bond forming reactions. 3 With regard to the latter, vinyl sulfide derivatives which are substituted in the α- position with halogen, tin, selenium, etc., are particularly useful due to the ready formation of anions upon treatment with a variety of organometallic reagents. 3 d− 1 We report here ...

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