Homolytic reactive mass spectrometry of fullerenes: Interaction of C60 and C70 with organo-and organoelement mercurials in the electron impact ion source of a mass …

YI Lyakhovetsky, EA Shilova, VV Bashilov…

Index: Lyakhovetsky, Yury I.; Shilova, Elena A.; Bashilov, Vasily V.; Sokolov, Viatcheslav I.; Nekrasov, Yuri S.; Tumanskii, Boris L. Journal of Physical Chemistry A, 2009 , vol. 113, # 49 p. 13700 - 13710

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Citation Number: 11

Abstract

Interaction of C60 with organo-and organoelement mercurials (CF3HgBr, PhHgBr, p- CH3C6H4HgBr, p-CH3OC6H4HgCl, CF3HgPh, Ph2Hg,(o-carborane-9-yl) 2Hg,(m- carborane-9-yl) 2Hg,(p-carborane-9-yl) 2Hg, and (m-carborane-9-yl) HgCl) in the ionization chamber (IC) of the electron impact (EI) ion source of a mass spectrometer at 250− 300° C results in the transfer of the corresponding organic or organoelement radicals from the ...