Recueil des Travaux Chimiques des Pays-Bas

Sulfenylated cyclic β??keto esters and cyclic β??diketones; synthesis and reactions with nucleophiles

BJM Jansen

Index: de Groot,A.; Jansen,B.J.M. Recueil des Travaux Chimiques des Pays-Bas, 1979 , vol. 98, p. 487 - 492

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Citation Number: 4

Abstract

Abstract Quenching the enolates of cyclic β-diketones or 2-oxocycloalkanecarboxylates with phenylsulfenyl chloride or methylsulfenyl chloride produces the corresponding x- sulfenylated products. Nucleophilic attack on these x-sulfenylated 1, 3-dicarbonyl compounds produces regiospecific sulfenylated linear dicarboxylic acids, acid esters, diesters or oxo esters suitable for further chemical transformation, this has been ...