Self??Assembly of 3, 6??Bis (4??triazolyl) pyridazine Ligands with Copper (I) and Silver (I) Ions: Time??Dependant 2D??NOESY and Ultracentrifuge Measurements

B Happ, GM Pavlov, E Altuntas, C Friebe…

Index: Happ, Bobby; Pavlov, Georges M.; Altuntas, Esra; Friebe, Christian; Hager, Martin D.; Winter, Andreas; Goerls, Helmar; Guenther, Wolfgang; Schubert, Ulrich S. Chemistry - An Asian Journal, 2011 , vol. 6, # 3 p. 873 - 880

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Citation Number: 13

Abstract

Abstract Two 3, 6-bis (R-1H-1, 2, 3-triazol-4-yl) pyridazines (R= mesityl, monodisperse (CH 2 [BOND] CH 2 O) 12 CH 3) were synthesized by the copper (I)-catalyzed azide–alkyne cycloaddition and self-assembled with tetrakis (acetonitrile) copper (I) hexafluorophosphate and silver (I) hexafluoroantimonate in dichloromethane. The obtained copper (I) complexes were characterized in detail by time-dependent 1D [1 H, 13 C] and 2D [1 H-NOESY] NMR ...