One-step synthesis of α-pyrones from acyl chlorides by the Stille reaction
J Thibonnet, M Abarbri, JL Parrain…
Index: Thibonnet, Jerome; Abarbri, Mohamed; Parrain, Jean-Luc; Duchene, Alain The Journal of organic chemistry, 2002 , vol. 67, # 11 p. 3941 - 3944
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Citation Number: 50
Abstract
The α-pyrones constitute an important class of biologically active compounds, and their synthesis has been a focus of considerable attention in synthetic organic chemistry 1 as well as in medicinal chemistry. 2 In the past decade, numerous methods reported for the synthesis of these structures utilize halolactonization or transition metals (Ag, Hg, Rh, Pd) to promote intramolecular addition of carboxylic acid to alkynes. 3 In general, these reactions of 4-alkynoic acids occur with ...
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