über die Inhaltsstoffe des grünen Knollenblätterpilzes, LVIII. Einige vom Ketophalloidin abgeleitete, in der biochemischen Forschung anwendbare Dithiolane

…, A Deboben, H Faulstich

Index: Wieland, Theodor; Deboben, Axel; Faulstich, Heinz Liebigs Annalen der Chemie, 1980 , # 3 p. 416 - 424

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Abstract

Abstract Ketophalloidin,[Cyclo (L-alanyl-D-threonyl-L-cysteinyl-4-allo-hydroxy-L-prolyl-L- alanyl-2-mercapto-L-tryptophyl-4-oxo-L-norvalyl)-cyclo (3 [RIGHTWARDS ARROW] 6) sulfid](2), aus Phalloidin (1) durch Periodatoxidation erhalten, wurde mit 2, 3- Dimercaptopropionsäure zur Dithiolancarbonsäure 3 oder mit 3-Amino-1, 2-propandithiol zum (Aminomethyl) dithiolan 4 umgesetzt. Verbindung 4 diente als Ausgangssubstanz für ...

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