Diversity synthesis using the complimentary reactivity of rhodium (II)-and palladium (II)-catalyzed reactions
A Ni, JE France, HML Davies
Index: Ni, Aiwu; France, Jessica E.; Davies, Huw M. L. Journal of Organic Chemistry, 2006 , vol. 71, # 15 p. 5594 - 5598
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Citation Number: 20
Abstract
Rhodium (II)-catalyzed reactions of aryldiazoacetates can be conducted in the presence of iodide, triflate, organoboron, and organostannane functionality, resulting in the formation of a variety of cyclopropanes or CH insertion products with high stereoselectivity. The combination of the rhodium (II)-catalyzed reaction with a subsequent palladium (II)-catalyzed Suzuki coupling offers a novel strategy for diversity synthesis.
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