The Journal of Organic Chemistry

Synthesis of ketamine metabolites I and II and some anomalous reactions of 6-bromoketamine

RF Parcell, JP Sanchez

Index: Parcell, Robert F.; Sanchez, Joseph P. Journal of Organic Chemistry, 1981 , vol. 46, # 25 p. 5055 - 5060

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Citation Number: 17

Abstract

Two metabolites of the drug ketamine, 2-(2-chlorophenyl)-2-(methylamino) cyclohexanone hydrochloride (l), la have been synthesized. They are the N-demethyl compound, metabolite I (131, and the N-demethyl-5, 6-dehydro analogue, metabolite I1 (15). Three bromo ketones derived from ketamine have also been synthesized and their relative configurations assigned. In addition, attempted dehydrohalogenation of axial 2-bromoketamine (2a) with ...

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