The First Example of Activation of Molecular Oxygen by Nickel in Ni??Al Hydrotalcite: A Novel Protocol for the Selective Oxidation of Alcohols
BM Choudary, ML Kantam, A Rahman…
Index: Choudary; Kantam, M. Lakshmi; Rahman, Ateeq; Reddy, Ch. Venkat; Rao, K. Koteswara Angewandte Chemie - International Edition, 2001 , vol. 40, # 4 p. 763 - 766
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Citation Number: 214
Abstract
Abstract NiO in association with aluminum oxide has been identified by temperature- programmed reduction as the active species in the Ni–Al hydrotalcite catalyst that oxidizes α- ketols as well as benzylic and allylic alcohols to their corresponding carbonyl compounds in oxygen in quantitative yields under mild reaction conditions (see scheme).
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