Conformational analysis, spectral and catalytic properties of 1, 3-thiazolidines, ligands for acetophenone hydrosilylation with diphenylsilane

…, DA De Vekki, EP Studentsov, NK Skvortsov

Index: Skvortsov; Uvarov; De Vekki; Studentsov Russian Journal of General Chemistry, 2010 , vol. 80, # 10 p. 2007 - 2021

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Citation Number: 3

Abstract

Abstract 2-Aryl-and 2-furyl-4-carboxy-1, 3-thiazolidines were synthesized. Their spectral properties were studied, and conformational analysis was performed. It was shown that they exist in solution as an equilibrium of neutral and zwitter-ion forms. The influence of the nature of substitutents and of their location in a benzene ring of thiazolidines as ligands of rhodium complexes on acetophenone hydrosilylation with diphenylsilane was examined. ...