Synthesis and properties of 1-dinitromethyl-3-R-1, 2, 4-triazoles

…, IV Dmitrienko, EY Glazkova, IV Tselinskii

Index: Kofman; Trubitsyn; Dmitrienko; Glazkova; Tselinskii Russian Journal of Organic Chemistry, 2007 , vol. 43, # 5 p. 758 - 764

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Citation Number: 3

Abstract

Abstract Reductive denitration of 1-trinitromethyl-3-R-1, 2, 4-triazoles by KI or NH 2 OH followed by the treatment of the formed 1-dinitromethyl-3-R-1, 2, 4-triazoles salts with sulfuric acid yielded dinitromethyl compounds (R= H, N 3, Cl, NO 2), sufficiently strong CH-acids (pK a 1.37–0.12) whose typical reactions are similar to those of gem-dinitrocompounds from the aliphatic series. The spectral data and the analysis of correlation relations between pK a ...