Diamond??Shaped [Ag4] 4+ Cluster Encapsulated by Silicotungstate Ligands: Synthesis and Catalysis of Hydrolytic Oxidation of Silanes

Y Kikukawa, Y Kuroda, K Yamaguchi…

Index: Kikukawa, Yuji; Kuroda, Yoshiyuki; Yamaguchi, Kazuya; Mizuno, Noritaka Angewandte Chemie - International Edition, 2012 , vol. 51, # 10 p. 2434 - 2437

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Citation Number: 63

Abstract

The design and synthesis of well-defined polynuclear metal or metal–oxygen clusters have attracted much attention in many fields of science such as catalysis, magnetism, electrochemistry, and photochemistry.[1] Generally, well-defined polynuclear clusters have been synthesized by using structuredirecting agents such as oxygen-and/or nitrogen-donor organic ligands.[1] Polyoxometalates (POMs) are a large family of anionic metal–oxygen ...

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