Experimental and theoretical studies on bis (chlorocarbonyl) trisulfane, ClC (O) SSSC (O) Cl
…, MV Cozzarín, CO Della Védova, RM Romano
Index: Tobon, Yeny A.; Cozzarin, Melina V.; Della Vedova, Carlos O.; Romano, Rosana M. Journal of Molecular Structure, 2009 , vol. 930, # 1-3 p. 37 - 42
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Abstract
Bis (chlorocarbonyl) trisulfane, ClC (O) SSSC (O) Cl, was prepared by the reaction of (CH3) 2CHOC (S) SC (S) OCH (CH3) 2 and SO2Cl2 at 65° C. The compound was characterized and identified by vibrational spectroscopy, GC–MS, matrix isolation and photochemical studies as well as by quantum chemical calculations. Matrix photochemical studies and vibrational spectra were interpreted in terms of the presence of three forms with syn- ...
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