A duality of mechanism in the hydrolysis of acyclic phosphoranes

N Lowther, CD Hall

Index: Lowther, Nicholas; Hall, C. Dennis Journal of the Chemical Society, Chemical Communications, 1985 , # 19 p. 1303 - 1305

Full Text: HTML

Citation Number: 0

Abstract

A Duality of Mechanism in the Hydrolysis of Acyclic Phosphoranes ... Nicholas Lowther and C. Dennis Hall* Department of Chemistry, King's College, Strand, London WC2R 2LSf U. K. ... Acyclic phosphoranes, Ar,P(OR)5-, with n = 0-3 are shown to hydrolyse in neutral conditions by an SNI (P) mechanism for n = 1, 2, and 3 but by an sN2 (P) or addition-elimination mechanism for n = 0; this is analogous to the classical SN1 vs. SN2 mechanisms observed for ...

Related Articles:

Electroreduction of triphenylphosphine dichloride and the efficient one-pot reductive conversion of phosphine oxide to triphenylphosphine

[Yano, Tomotake; Kuroboshi, Manabu; Tanaka, Hideo Tetrahedron Letters, 2010 , vol. 51, # 4 p. 698 - 701]

Electroreduction of tetra-coordinate phosphonium derivatives; one-pot transformation of triphenylphosphine oxide into triphenylphosphine

[Kuroboshi, Manabu; Yano, Tomotake; Kamenoue, Shogo; Kawakubo, Hiromu; Tanaka, Hideo Tetrahedron, 2011 , vol. 67, # 32 p. 5825 - 5831]

Electroreduction of tetra-coordinate phosphonium derivatives; one-pot transformation of triphenylphosphine oxide into triphenylphosphine

[Kuroboshi, Manabu; Yano, Tomotake; Kamenoue, Shogo; Kawakubo, Hiromu; Tanaka, Hideo Tetrahedron, 2011 , vol. 67, # 32 p. 5825 - 5831]

The influence of the sacrificial anode nature on the mechanism of electrochemical arylation and alkylation of white phosphorus

[Yakhvarov; Budnikova; Tazeev; Sinyashin Russian Chemical Bulletin, 2002 , vol. 51, # 11 p. 2059 - 2064]

A novel imido-transfer reaction of aldehydes with Ph 3 P NTs using RuCl 2 (PPh 3) 3 as catalyst

[Jain, Suman L.; Sharma, Vishal B.; Sain, Bir Tetrahedron Letters, 2004 , vol. 45, # 22 p. 4341 - 4343]

More Articles...