The Synthesis of Sulfinylphthalimides and Their Reactions With Some Nucleophiles in Dioxane

YS Bozkurt, H Kutuk

Index: Bozkurt, Yasemin Soydas; Kutuk, Halil Phosphorus, Sulfur and Silicon and the Related Elements, 2011 , vol. 186, # 11 p. 2250 - 2257

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Abstract

Abstract In this study, some N-(p-substituted-arylsulfinyl) phthalimides (1a–1e) were synthesized. The synthesized compounds were examined with respect to their substitution reactions with sodium ethoxide, sodium methoxide, methylamine, and t-butylamine in dioxane. The substituent effect was investigated at 30.0±0.1° C. The activation entropy was also studied, and negative ΔS≠ values were obtained. Configuration inversions were ...