The introduction of SCF3 into aromatic substrates using CuSCF3 and alumina-supported CuSCF3

JH Clark, CW Jones, AP Kybett, MA McClinton…

Index: Clark, James H.; Craig, W. Jones; Kybett, Adrian P.; McClinton, Martin A.; Miller, Jack M.; et al. Journal of Fluorine Chemistry, 1990 , vol. 48, # 2 p. 249 - 255

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Citation Number: 61

Abstract

Abstract Trifluoromethylthiocopper (I) has been readily prepared from the silver analogue, using a metathetical reaction with copper (I) bromide. Homogeneous CuSCF 3 and the supported reagent CuSCF 3-alumina have been compared in their reactivity towards aryl iodides, in order to form trifluoromethylaryl sulphides in good yields.

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