Complexes between N-bromosuccinimide and quaternary ammonium bromides and their role in the addition of bromine to olefins

…, SA Hart, WM Moore, SD Ross, L Eberson

Index: Finkelstein, Manuel; Hart, Shirley A.; Moore, W. Michael; Ross, Sidney D.; Eberson, Lennart Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3548 - 3551

Full Text: HTML

Citation Number: 18

Abstract

SBr[C2HJ4NBr 2: l 126-128 59 SBr[C2H6I4NBr 1: l 103 dec 97 SBr C6H5CH2N (C2H6) 3Br 1: l 109-110 89 nisms.” 13 Our recent work14-18 has demonstrated that both SBr and N- chlorosuccinimide (SC1) can participate in rapid electron-transfer reactions with an appropriate nucleophile, eg, the succinimide anion. With SBr the electron transfer probably occurs in a complex formed from SBr and a quaternary ammonium succinimide16 and ...

Related Articles:

tert-Butylacetylene revisited. Improved synthesis. Methyl migration during bromination

[Collier,W.L.; Macomber,R.S. Journal of Organic Chemistry, 1973 , vol. 38, p. 1367 - 1369]

Reactions of a graded set of radicals with N-bromosuccinimide; two transition states

[Tlumak, Robert L.; Skell Philip S. Journal of the American Chemical Society, 1982 , vol. 104, # 25 p. 7267 - 7274]

The Reaction of t-Butylethylene and 1-Hexene with Bromine in Methanol1a

[Puterbaugh; Newman Journal of the American Chemical Society, 1957 , vol. 79, p. 3469]

The chemistry of 1, 8-naphthalenedicarboximidyl and phthalimidyl radicals

[Day, J. C.; Govindaraj, N.; McBain, D. S.; Skell, P. S.; Tanko, J. M. Journal of Organic Chemistry, 1986 , vol. 51, # 25 p. 4959 - 4963]

Photo-induced alkoxybromination of olefins by N, N'-dibromo-2, 5-piperazinedione.

[Sera, Akira; Yamada, Hiroshi; Itoh, Kuniaki Bulletin of the Chemical Society of Japan, 1980 , vol. 53, # 1 p. 219 - 221]

More Articles...