Synthesis, Structural Characterization, Reactivity, and Catalytic Properties of Copper (I) Complexes with a Series of Tetradentate Tripodal Tris (pyrazolylmethyl) amine …
…, A Prieto, E Álvarez, C Maya, MC Nicasio…
Index: Haldon, Estela; Alvarez, Eleuterio; Nicasio, M. Carmen; Perez, Pedro J. Inorganic Chemistry, 2012 , vol. 51, # 15 p. 8298 - 8306
Full Text: HTML
Citation Number: 9
Abstract
A series of cationic and neutral copper (I) complexes with tris (pyrazolylmethyl) amine ligands (Tpa x) have been prepared and characterized. The structures in the solid state reveal their polynuclear nature and a μ2: κ2: κ1-coordination mode for the Tpa x ligands, whereas NMR studies agree with the existence of fluxional behavior in solution.
Related Articles:
[Phillips, Dean P.; Zhu, Xue-Feng; Lau, Thomas L.; He, Xiaohui; Yang, Kunyong; Liu, Hong Tetrahedron Letters, 2009 , vol. 50, # 52 p. 7293 - 7296]
Scope and selectivity in palladium-catalyzed directed C–H bond halogenation reactions
[Tetrahedron, , vol. 62, # 49 p. 11483 - 11498]