Reductive cleavage of hydroxylamine derivatives by dihydrolipoic acid-iron (II)
…, M Kijima, T Endo, M Okawara
Index: Nambu, Yoko; Kijima, Masashi; Endo, Takeshi; Okawara, Makoto Journal of Organic Chemistry, 1982 , vol. 47, # 16 p. 3066 - 3069
Full Text: HTML
Citation Number: 18
Abstract
The reduction of hydroxylamine derivatives was attempted with dihydrolipoic acid-iron (I1) to obtain cor-responding alcohols and amines in high yields under a mild condition (pH 9.1, 30" C). Some dithiols other than dihydrolipoic acid which cyclize to form disulfides were also useful for the reduction, and ferrous ion worked as an effective catalyst. From the spectroscopic and kinetic studies, the reduction was found to proceed through 1: 1: 1 ...
Related Articles:
Chromyl complexes in the direct epoxidation of alkenes
[Miyaura, N.; Kochi, J. K. Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2368 - 2378]
Mechanism of anodic cleavage of benzyl ethers
[Boyd, Jean W.; Schmalzl, Paul W.; Miller, Larry L. Journal of the American Chemical Society, 1980 , vol. 102, # 11 p. 3856 - 3862]
[Glover, Stephen A.; Golding, Stephen L.; Goosen, Andre; McCleland, Cedric W. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 10 p. 2479 - 2483]
1, 3-Dialkyltriazenes: tautomeric equilibria and rates and products of decomposition
[Smith, Richard H.; Wladkowski, Brian D.; Mehl, Andrew F.; Cleveland, Michael J.; Rudrow, Elizabeth A.; et al. Journal of Organic Chemistry, 1989 , vol. 54, # 5 p. 1036 - 1042]
Bakers' yeast mediated synthesis of 4-deoxy-D-lyxo-hexopyranose (4-deoxy-D-mannose)
[Fronza, Giovanni; Fuganti, Claudio; Grasselli, Piero; Servi, Stefano Journal of Organic Chemistry, 1987 , vol. 52, # 10 p. 2086 - 2089]