Simultaneous Presence of Both Open Metal Sites and Free Functional Organic Sites in a Noncentrosymmetric Dynamic Metal–Organic Framework with Bimodal …

…, B Joarder, AS Roy, M Islam, S Kumar

Index: Saha, Rajat; Joarder, Biplab; Roy, Anupam Singha; Manirul Islam, Sk.; Kumar, Sanjay Chemistry - A European Journal, 2013 , vol. 19, # 49 p. 16607 - 16614

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Citation Number: 27

Abstract

Abstract Assimilation of open metal sites (OMSs) and free functional organic sites (FOSs) with a framework strut has opened up a new route for the fabrication of novel metal–organic materials, thereby providing a unique opportunity to explore their multiple functionalities. A new metal–organic framework (MOF),{[Cu (ina) 2 (H 2 O)][Cu (ina) 2 (bipy)]⋅ 2 H 2 O} n (1)(ina= isonicotinate, bipy= 4, 4′-bipyridine), has been synthesized and characterized. ...

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