Canadian Journal of Chemistry

SULFONATE ESTERS OF α-CHLOROALDOXIMES, ALDOXIMES, AND AMIDOXIMES VIA" SULFENE" ADDITION

WE Truce, AR Naik

Index: Truce,W.E.; Naik,A.R. Canadian Journal of Chemistry, 1966 , vol. 44, p. 297 - 305

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Citation Number: 11

Abstract

Reaction of aromatic nitrile oxides with methanesulfonyl and benzylsulfonyl chlorides in the presence of triethylamine yielded sulfonate esters of α-chloroaldoximes. Under the same reaction conditions, aldoximes yielded sulfonate esters, which decomposed to nitriles, and amidoximes yielded amidoxime O-sulfonates, which were also prepared by the action of ammonium hydroxide on. Chemical as well as nuclear magnetic resonance spectroscopic ...

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