4-MeC6H4I-Mediated Efficient α-Tosyloxylation of Ketones with Oxone® and p-Toluenesulfonic Acid in Acetonitrile
A Tanaka, H Togo
Index: Tanaka, Ayumi; Togo, Hideo Synlett, 2009 , # 20 p. 3360 - 3364
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Citation Number: 14
Abstract
Abstract Various alkyl aryl ketones, dialkyl ketones, and cycloheptanone were efficiently converted into the corresponding α-tosyloxy ketones in good yields by using Oxone® and p- toluenesulfonic acid monohydrate in the presence of p-iodotoluene in acetonitrile. 4- Methoxyacetophenone and 2-acetylthiophene bearing an electron-rich aromatic group could be also converted into the corresponding α-tosyloxyketones smoothly in good yields ...
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