Tetrahedron letters

An efficient route to heteroarene-substituted vinyl-and allyl-silanes via palladium-phosphine complex catalyzed cross-coupling

A Minato, K Suzuki, K Tamao, M Kumada

Index: Minato, Akio; Suzuki, Keizo Tetrahedron Letters, 1984 , vol. 25, # 1 p. 83 - 86

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Citation Number: 42

Abstract

Abstract Heteroarene-substituted vinyl-and allyl-silanes were obtained in good yields by the cross-coupling reaction of either heteroaryl Grignard reagents with halovinyl-and haloallyl- silanes or, alternatively, silyl-and silylmethyl-substituted vinylmetallic reagents with heteroaryl halides in the presence of PdCl 2 (dppb) as a catalyst.