Chemistry–A European Journal

Substituent Effects on the Electrophilic Activity of Nitroarenes in Reactions with Carbanions

S Błażej, M Mąkosza

Index: Blazej, Sylwia; Makosza, Mieczyslaw Chemistry - A European Journal, 2008 , vol. 14, # 35 p. 11113 - 11122

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Citation Number: 17

Abstract

Abstract The effect on electrophilic activity of substituents located para, ortho, and meta to the nitro group of nitrobenzenes was determined by using vicarious nucleophilic substitution of hydrogen (VNS) with the carbanion of chloromethyl phenyl sulfone (1) as the model process. Values for the relative activities of substituted nitroarenes are given relative to nitrobenzene, which was taken as the standard. This process was chosen as a model ...

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