Low??Temperature Ag/Pd??Catalyzed Decarboxylative Cross??Coupling of Aryl Triflates with Aromatic Carboxylate Salts

LJ Goossen, PP Lange, N Rodriguez…

Index: Goossen, Lukas J.; Lange, Paul P.; Rodriguez, Nuria; Linder, Christophe Chemistry - A European Journal, 2010 , vol. 16, # 13 p. 3906 - 3909

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Citation Number: 91

Abstract

Metal-catalyzed decarboxylative couplings are evolving into powerful synthetic tools for the regioselective formation of CÀC bonds. New protocols for Heck-type reactions,[1] oxidative arylations,[2] redox-neutral couplings,[3] and allylations [4] have provided innovative atom- economic and wasteminimized pathways among others to biaryls, vinyl arenes, and aryl ketones starting from readily available carboxylic acids.[5] These transformations have ...