Chemoenzymatic Synthesis of α-Hydroxy-β-methyl-γ-hydroxy Esters: Role of the Keto− Enol Equilibrium To Control the Stereoselective Hydrogenation in a Key Step
CDF Milagre, HMS Milagre, PJS Moran…
Index: Buksha, Svitlana; Coumbarides, Gregory S.; Dingjan, Marco; Eames, Jason; Suggate, Michael J.; Weerasooriya, Neluka Journal of Labelled Compounds and Radiopharmaceuticals, 2005 , vol. 48, # 5 p. 337 - 352
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Citation Number: 14
Abstract
... The Journal of Organic ... A. The relative configuration of 18 was determined as 3,4-cis-4,5-cis which is supported by J constants from ... of Relative Configuration of 18. Further determination of the absolute configuration of 18 was obtained using the chiral auxiliary reagent (S)-MPA (α ...
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