Tetrahedron

Stereoselective synthesis of α-substituted ulosonic acids by magnesio-reformatsky reactions

R Csuk, C Schröder, C Krieger

Index: Csuk, Rene; Schroeder, Christina; Krieger, Claus Tetrahedron, 1997 , vol. 53, # 38 p. 12947 - 12960

Full Text: HTML

Citation Number: 8

Abstract

A new method of homologation of aldonolactones allowing the incorporation of propionate units with excellent chemo-and stereoselectivity is performed by the magnesium-graphite mediated reaction between Oppolzer sultam derived α-halogenated amides and an aldonolactone.