Stable unsymmetrical diphosphenes
CN Smit, TA Van der Knaap, F Bickelhaupt
Index: Smit, C.N.; van der Knaap, Th.A.; Bickelhaupt, F. Tetrahedron Letters, 1983 , vol. 24, # 19 p. 2031 - 2034
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Citation Number: 39
Abstract
Abstract Variation of the ortho-alkyl substituents in diaryldiphosphenes revealed that their stability is determined by steric hindrance. By suitable combinations of ortho-substituents, it was therefore possible to prepare the first relatively stable unsymmetrical diphosphenes ( ...
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