Nickel??Catalyzed Amination of Aryl Sulfamates

SD Ramgren, AL Silberstein, Y Yang…

Index: Ramgren, Stephen D.; Silberstein, Amanda L.; Yang, Yang; Garg, Neil K. Angewandte Chemie - International Edition, 2011 ,  vol. 50,  # 9  p. 2171 - 2173

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Citation Number: 80

Abstract

Carbon–nitrogen bonds are ubiquitous in medicinal agents and natural products.[1] Transition metal-catalyzed amination reactions, pioneered by Buchwald and Hartwig, are amongst the most powerful methods available for accessing these motifs.[1] Copper-and palladium-mediated aminations of aryl halides and triflates are now well-established,[1] and examples of mesylate [2] and tosylate [3] aminations have been reported. Most recent ...