Synthesis and characterization of stable hypervalent carbon compounds (10-C-5) bearing a 2, 6-bis (p-substituted phenyloxymethyl) benzene ligand

…, Y Yamamoto, M Minoura, D Hashizume…

Index: Akiba, Kin-Ya; Moriyama, Yuji; Mizozoe, Mitsuhiro; Inohara, Hideki; Nishii, Takako; Yamamoto, Yohsuke; Minoura, Mao; Hashizume, Daisuke; Iwasaki, Fujiko; Takagi, Nozomi; Ishimura, Kazuya; Nagase, Shigeru Journal of the American Chemical Society, 2005 , vol. 127, # 16 p. 5893 - 5901

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Citation Number: 46

Abstract

X-ray analysis of bis (p-fluorophenyl) methyl cation bearing a 2, 6-bis (p-tolyloxymethyl) benzene ligand showed a symmetrical structure (10-C-5) where the two CO distances are identical, although the distance (2.690 (4) Å) is longer than those (2.43 (1) and 2.45 (1) Å) of 1, 8-dimethoxy-9-dimethoxymethylanthracene monocation, which was recently reported by us. However, X-ray analysis of the more stable aromatic xanthylium cation with the same ...