Journal of the American Chemical Society

Total syntheses of (-)-macrolactin A,(+)-macrolactin E, and (-)-macrolactinic acid: an exercise in stille cross-coupling chemistry

AB Smith, GR Ott

Index: McDermott, Todd S.; Mortlock, Andrew A.; Heathcock, Clayon H. Journal of Organic Chemistry, 1996 ,  vol. 61,  # 2  p. 700 - 709

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Citation Number: 105

Abstract

... Journal of the ... Previous experience in the rapamycin/demethoxyrapamycin 6,9h - j area suggested that esterification followed by an intramolecular Stille cross ... desilylation conditions known to be effective with allylic TBS ethers in highly unsaturated systems (eg, HCO 2 H/THF/H ...