Highly Selective and Efficient Lewis Acid–Base Catalysts Based on Lanthanide??Containing Polyoxometalates for Oximation of Aldehydes and Ketones

S Zhao, L Huang, YF Song

Index: Zhao, Shen; Huang, Lujiang; Song, Yu-Fei European Journal of Inorganic Chemistry, 2013 , # 10-11 p. 1659 - 1663

Full Text: HTML

Citation Number: 3

Abstract

Aldoximes and ketoximes have been widely utilized in medicine, industry, and analytical chemistry, and they are very useful and versatile intermediates in synthetic organic chemistry. For example, aldoximes and ketoximes can be reduced to amines or oxidized to nitrile oxides, which are important precursors.1,2 In general, these oximes can be industrially synthesized by nucleophilic addition of various mineral salts of hydroxylamine [(NH 2 OH) x ·H x B, B = ...