Hydroxyl radical-induced oxidation of diethyl ether in oxygenated aqueous solution. A product and pulse radiolysis study
MN Schuchmann, C Von Sonntag
Index: Schuchmann, Man Nien; Sonntag, Clemens von Journal of Physical Chemistry, 1982 , vol. 86, # 11 p. 1995 - 2000
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Citation Number: 57
Abstract
The reactions of peroxyl radicals derived from diethyl ether were investigated by product analyses and pulse-radiolytic techniques. The products and their G values [in brackets] in the y radiolysis of diethyl ether M) in NzO/Oz-saturated aqueous solutions at 0.43 W kg-I are acetaldehyde [0.6], ethanol [0.6], ethyl acetate [2.8], ethyl formate [0.7], formaldehyde [0.4], hydrogen peroxide [2.1], 1-ethoxyethyl hydroperoxide [1.2], and 2-ethoxyacetaldehyde [- ...
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