Dinuclear Palladium (III) Complexes with a Single Unsupported Bridging Halide Ligand: Reversible Formation from Mononuclear Palladium (II) or Palladium (IV) …

JR Khusnutdinova, NP Rath…

Index: Khusnutdinova, Julia R.; Rath, Nigam P.; Mirica, Liviu M. Angewandte Chemie - International Edition, 2011 , vol. 50, # 24 p. 5532 - 5536

Full Text: HTML

Citation Number: 31

Abstract

Along with the well-known involvement of Pd0 and PdII oxidation states in a large number of palladium-catalyzed reactions,[1] recent reports have proposed the intermediacy of less- common PdIV and PdIII oxidation states in several chemical transformations.[2] Among these systems, dinuclear and mononuclear PdIII complexes have been shown to act as active intermediates in both two-and one-electron oxidative CÀH functionalization and ...