Palladium??Catalyzed Formation of C= C Bonds: A Regioselective Strategy for the Synthesis of 2??Vinylfurans by 1, 2??H Shift of Palladium–Carbene Complexes

H Zhan, X Lin, Y Qiu, Z Du, P Li, Y Li…

Index: Zhan, Haiying; Lin, Xiulian; Qiu, Yanying; Du, Zuodong; Li, Peixian; Li, Yongjian; Cao, Hua European Journal of Organic Chemistry, 2013 , # 12 p. 2284 - 2287

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Citation Number: 10

Abstract

Abstract A convenient method to synthesize vinylfurans through a palladium-catalyzed cyclization/1, 2-H shift sequence under mild conditions is described. This is an efficient strategy to synthesize 2-vinylfurans from ene–yne ketones, and the corresponding products are obtained in good yields.