Arylphosphonylation and arylazidation of activated alkenes
W Kong, E Merino, C Nevado
Index: Kong, Wangqing; Casimiro, Maria; Fuentes, Noelia; Merino, Estibaliz; Nevado, Cristina Angewandte Chemie - International Edition, 2013 , vol. 52, # 49 p. 13086 - 13090 Angew. Chem., 2013 , vol. 125, # 49 p. 13324 - 13328,5
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Citation Number: 64
Abstract
Abstract Two radical-mediated processes of activated alkenes, namely arylphosphonylation and arylazidation, are described. The difunctionalization of alkenes by a tandem process that involves radical addition, 1, 4-aryl migration, and desulfonylation generates α-aryl-β-
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