Free radical rearrangements of organocobaloximes: alkynyl to cycloalkylidene and hexenyl to cyclopentylmethyl

…, CJ Cooksey, MD Johnson, MJ Lewin, S Mitchell…

Index: Bougeard, Peter; Cooksey, Christopher J.; Johnson, Michael D.; Lewin, Melanie J.; Mitchell, Stewart; Owens, Paul A. Journal of Organometallic Chemistry, 1985 , vol. 288, p. 349 - 358

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Citation Number: 8

Abstract

Abstract Under irradiation by tungsten light in pyridine solution, several substituted alkylcobaloximes undergo rearrangement to more stable substituted alkyl-or alkenyl- cobaloximes. When the same reactions are carried out in the presence of carbon tetrachloride or chloroform, no rearranged organocobaloximes are obtained, but a variety of organic products are obtained derived from the interception of transient organic radicals ...