Journal of organometallic chemistry

Origine de l'étain formé durant les électrolyses dudichlorure de méthyphénylétain

M Engel, M Devaud

Index: Engel, Michele; Devaud, Marguerite Journal of Organometallic Chemistry, 1986 , vol. 307, p. 15 - 22

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Abstract

Abstract Studies of electroreduction of methylphenyltin dichloride a dihydride enabled us to follow the formation of bis (chloromethylphenyltin). This dimer decays rapidly in the solid state. Migration of a phenyl group and disproportionation of the resulting chrloromethyltin derivative intitiate the formation of amalgamated tin and trisubstituted organotin compounds during electrolysis of the dichloride.