Dalton Transactions

… on thioimides, R 2 C [double bond, length as m-dash] NSR and sulfur diimides, R 2 C [double bond, length as m-dash] NSN [double bond, length as m-dash] CR 2

RL Melen, DJ Eisler, RA Hewitt, JM Rawson

Index: Melen, Rebecca L.; Eisler, Dana J.; Hewitt, Rachel A.; Rawson, Jeremy M. Dalton Transactions, 2013 , vol. 42, # 11 p. 3888 - 3895

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Abstract

Reaction of Ph2CO and py2CO with Li [N (SiMe3) 2] and ArSCl (Ar= 2-O2NC6H4, 2, 4- (O2N) 2C6H3) yielded Ph2CNSAr (1a and 1b respectively) and py2CNSAr (2a and 2b respectively). Reaction of fluorenone, C12H8CO with Li [N (SiMe3) 2] and ArSCl under similar conditions afforded C12H8CNSAr (3a and 3b respectively). Whilst reaction of fluorenone with Li [N (SiMe3) 2] and SCl2 in a 2: 2: 1 ratio afforded the sulfur-diimide, ...