REACTION OF o-BENZENEDITHIOLS AND DERIVATIVES WITH PHOSPHORUS PENTACHLORIDE

DB Denney, DZ Denney, LT Liu

Index: Denney, Donald B.; Denney, Dorothy Z.; Liu, Lun-Tsu Phosphorus and Sulfur and the Related Elements, 1982 , vol. 13, p. 243 - 248

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Citation Number: 4

Abstract

Abstract Reaction of phosphorus pentachloride with thiocatechol, 4-methyl-1, 2- benzenedithiol and their trimethyl-silylated derivatives under a variety of conditions produced chlorodithiophosphites in which a 5-membered ring with two sulfurs is bonded to phosphorus. The other product of this reaction is probably an oligomeric disulfide derived from the original dithiol.