A versatile process for the syntheses of very long chain alkanes, functionalised derivatives and some branched chain hydrocarbons
…, S Mohammed, D Proctor, MC Whiting
Index: Brooke, Gerald M.; Burnett, Simon; Mohammed, Shahid; Proctor, David; Whiting, Mark C. Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 13 p. 1635 - 1645
Full Text: HTML
Citation Number: 94
Abstract
An earlier method for synthesising very long straight-chain alkanes of very specific lengths has been improved to give, in some cases, gram amounts of materials. Eleven compounds have been made: C98H198, C122H246, C162H326, C194H390, C198H398, C210H422, C242H486, C246H494, C258H518, C294H590 and C390H782. The self-condensation reaction of one of the intermediate aldehydes enabled two chain-branched hydrocarbons ...
Related Articles:
[Porter, Ned A.; Magnin, David R.; Wright, Bruce T. Journal of the American Chemical Society, 1986 , vol. 108, # 10 p. 2787 - 2788]
The synthesis of long-chain unbranched aliphatic compounds by molecular doubling
[Paynter, Oliver I.; Simmonds, Derek J.; Whiting, Mark C. Journal of the Chemical Society, Chemical Communications, 1982 , # 20 p. 1165 - 1166]
Permaleic acid: Baeyer–Villiger oxidation of cyclododecanone
[Bidd, Ilesh; Kelly, David J.; Ottley, Peter M.; Paynter, Oliver I.; Simmonds, Derek J.; Whiting, Mark C. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 7 p. 1369 - 1372]
[Wasserman, Harry H.; Gambale, Ronald J.; Pulwer, Mitchell J. Tetrahedron, 1981 , vol. 37, # 23 p. 4059 - 4067]
Permaleic acid: Baeyer–Villiger oxidation of cyclododecanone
[Bidd, Ilesh; Kelly, David J.; Ottley, Peter M.; Paynter, Oliver I.; Simmonds, Derek J.; Whiting, Mark C. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1983 , # 7 p. 1369 - 1372]