Azido, Triazolyl, and Alkynyl Complexes of Gold (I): Syntheses, Structures, and Ligand Effects

…, N Deligonul, JB Updegraff III, TG Gray

Index: Heckler, James E.; Deligonul, Nihal; Rheingold, Arnold L.; Gray, Thomas G. Chemical Communications, 2013 , vol. 49, # 53 p. 5990 - 5992

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Citation Number: 9

Abstract

Gold(I) triazolyl complexes are prepared in [3 + 2] cycloaddition reactions of (tertiary phosphine)gold(I) azides with terminal alkynes. Seven such triazolyl complexes, not previously prepared, are described. Reducible functional groups are accommodated. In addition, two new